The needed cabling
PC---USB2---------------------------------------------------------+
| |
| USB2 |
| |
Babyface Pro FS [cm]---ADAT IN<------------ADAT OUT---Presonus 1824C [cs]
\---ADAT OUT-------------ADAT IN---/
cm=clock master, BBF Pro FS (driver settings: clock source = internal)
cs=clock slave, Presonus (settings: clock source = ADAT IN)
It doesn't matter whether the Presonus supports standalone operation or not.
You can keep it connected via USB for operational reasons.
In the Audio Application (DAW, ...) simply load the RME driver, so that the BBF Pro FS is the main interface.
Would have been useful to know the whole setup (Windows machine or Apple).
Windows needs at least one WDM device for Windows sound and applications like Firefox without support for ASIO.
BR Ramses - HDSPe MADI FX, M-1620 Pro D, 12Mic, UFX III, ADI-2 Pro FS R BE, Nuendo 15, Win10 IoT Ent