What do you have now .. ADI-2 DAC or Pro FS, I become confused as subject and your text is mixing this, please clarify.
I don't understand what you mean with "5th ADAT port".
Could you kindly deliver a quick (maybe simple ASCII-) drawing, how the devices are connected?
ADI-2 * FS understands (automatically) both: ADAT and SPDIF protocol.
When ADAT is in use, the ADI-2 DAC/PRO FS picks automatically the 1st two channels out of the data stream.
But there would be problems with clock distribution recognizing sample rates over 48 kHz automatically.
With double and quad speed, port multiplexing is in place to achieve the bandwidth.
You need a 2ch protocol like AES or SPDIF where you have only two channels and where the sample can be detected, as there are only 2ch and the sample rate really switches between 44.1 - 192 kHz.
With ADAT and port multiplexing, you are bundling 2 or 4 ports of either 44.1 or 48 kHz to achieve the higher bandwidth which is needed to get 88.1 - 192 kHz.
Therefore, it is advised to use a 2ch protocol like AES or SPDIF to connect the ADI-2 * if you use sample rates over 48 kHz.
Maybe for playback of material in your music collection.
AFAIR - when using ADAT protocol - and if you have an ADI-2 Pro or ADI-2/4 Pro SE, then the device would pick the first two channels out of the ADAT stream for itself and the rest of the channels are unused, but would be forwarded transparently out on the ADAT port if you intend to connect other devices behind the ADI-2 Pro using ADAT.
BR Ramses - UFX III, 12Mic, XTC, M-1620 Pro D, RayDAT, ADI-2 Pro FS R BE, X10SRi-F, E5-1680v4, Win10