Topic: PCI vs. PCIe

I want to buy a Multiface II. There are plenty options to get it new, but since I have a brandnew PC I think I want a PCIe card to get it connected. What is the difference between both and does it make any sense to spend the extra money?

Windows PC -> Core i7 4x 2,8 GHz, 12 GB Ram, Asus Workstation Mainboard (no soundcard yet)
Macbook Pro -> Core2Duo 2, 2,4 GHz, 4 GB Ram, RME RPM, HDSPe

MSI X58 Pro i7@930, 12GB
W10 Pro x64, Reaper, Wavelab
5x MF II, 5x MF
E-mus and many other animals