+12dBu is the highest level that the XLRs will accept for 0dBfs, ie., without distortion. Up to that level you will not exceed the headroom of the signal path. It just so happens that with the preamp set to 0dB gain, that is the maximum level that the A-D converter can handle.
15dB pads are a very convenient value in this case, as this means that the XLRs inputs can then accept +27dBu, which means most (American) professional gear designed for a maximum output of +24dBu can be accommodated with 3dB to spare. That is, the equipment output will go into distortion before the input.
Note that while most pads are designed for 'mic' levels, their ratings will accommodate 'line' levels. Realise that +27dBu corresponds to 0.5 watt into 600 ohms. Check the power rating specs for the attenuator. But as an example, if the input impedance (resistance) of the pad is 1500 ohms, then a signal level of +27dBu (15V rms) across 1500 ohm is 0.15W dissipation. As the pad is balanced, most of this will be dissipated across two series input resistors, so the power dissipated in each is about 75mW. Most resistors have a minimum rating of a quarter watt namely 250mW, so in this sort of use they will be expected to handle line levels quite happily. But check the specs, anyway.
And make sure phantom power is turned off - most analog devices don't like encountering 48V phantom on their outputs.
Trimming the analog outputs on the desk will slightly degrade the signal to noise ration of the desk's output, but if the reference output level can be set to 'consumer' levels (nominal level of -10dBV) this will work. Remember that if accidentally driven hard, the input can still clip so always check the level in TotalMix or DigiCheck.
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